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Ring inversion in eucarvone

✍ Scribed by E. Cuthbertson; D.D. MacNicol

Publisher: Elsevier Science
Year: 1974
Tongue: French
Weight: 100 KB
Volume: 15
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)92330-5

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✦ Synopsis

Considerable attention1 has been directed towards the determination of conformations and conformational mobilities of simple seven-membered carbocycles which are fully saturated or have one or three endocyclic double bonds. On the other hand, the corresponding unfused systems possessing two double bonds in the ring have received little attention, though molecular mechanics calculations ' on cyclohepta-1,3-diene (I) indicate an extremely high degree of molecular mobility for this molecule.

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