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Ring expansions of 1-Haloethynyl-2-methylcyclopentanols

โœ Scribed by Xavier Herault; Edward Mc Nelis


Book ID
103397062
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
670 KB
Volume
52
Category
Article
ISSN
0040-4020

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Ring Expansions of 2-Haloethynyl-2-norbo
โœ Elsa Djuardi; Pakorn Bovonsombat; Edward Mc Nelis ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 785 KB

Z-Haloethvnvl-2-norbomanols react with iodine and Kosefs reagent in acetonitrile to afford two ring-expanded products, 2-[(Z)-haloiodomethylidene]bicyclo[3.2.&ctan-3-one and 3-[(Z)haloiodomethylidene]bicyclo[3.2.l]octan-Zone. These results contrast with the 2-haloethynyl-2bomanols whiih lead to the