Ring expansion of alkynyl cyclopropanes to highly substituted cyclobutenes via a N-sulfonyl-1,2,3-triazole intermediate
✍ Scribed by Liu, Renhe ;Zhang, Min ;Winston-McPherson, Gabrielle ;Tang, Weiping
- Book ID
- 119946603
- Publisher
- Royal Society of Chemistry
- Year
- 2013
- Tongue
- English
- Weight
- 692 KB
- Volume
- 49
- Category
- Article
- ISSN
- 1359-7345
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📜 SIMILAR VOLUMES
In the presence of excess Bu2BOTf to promote anti-selectivity, an asymmetric aldol reaction with a homochiral terpenoid-derived 1,3-oxazin-2-one as the chiral control element results unexpectedly in ring cleavage by an intramolecular process to form a N-substituted tetrahydro-l,3oxazine-2,4-dione in
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