Ring Expansion of a 1,2-Diphosphaspiropentane: Formation of a Diphosphamethylenecyclobutane and a 1,4-Diphosphanorbornadiene
β Scribed by Catherine Garot; Dr. Guita Etemad-Moghadam; Prof. Dr. Jean-Paul Declercq; Dr. Antoine Dubourg; Dr. Max Koenig
- Publisher
- John Wiley and Sons
- Year
- 1992
- Tongue
- English
- Weight
- 259 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0044-8249
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mation of the ( Z ) isomer supports the assumption that in compound 13 (and probably also in 12) the substituents at the noncoordinated C=C double bond are arranged cis. The rhodium-containing product of the reaction of 8 or 13 with acetic acid is the chelate complex 17,[\*] which can be reconverted