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Ring cleavage of camphor derivatives: formation of chiral synthons for natural product synthesis

โœ Scribed by Hutchinson, J. H.; Money, T.; Piper, S. E.

Book ID
118259136
Publisher
NRC Research Press
Year
1986
Tongue
French
Weight
463 KB
Volume
64
Category
Article
ISSN
0008-4042

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The chiral half-ester 2 obtained by asymmetric hydrolysis of the symmetric diester 1 with pig liver esterase has been shown to be a versatile synthon for various chiral cyclohexane derivatives. The stereocontrolled introduction of polyfunctional groups on cyclohexane ring has been well developed in