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Ring cleavage and ring expansion of indoles by superoxide ion

✍ Scribed by É. Balogh-Hergovich; G. Speier

Publisher: Elsevier Science
Year: 1982
Tongue: French
Weight: 190 KB
Volume: 23
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)85631-2

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✦ Synopsis

The reaction of indoles (A) with superoxide ion resulted in ring cleavage to give o-formyl and o-acylaminoketones -(A) or N-acylanthranilic acid (s) and ring expansion yielding 2-quinolones (3). All reactions are chemiluminescent

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