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Ring-Chain Tautomerism in Organic Synthesis: Synthesis of Heterocyclic Enamines from a Novel and Practical Formal Ring Transformation Reaction of Lactones.

✍ Scribed by Mei-Xiang Wang; Yong Liu; Hong-Yun Gao; Yan Zhang; Chu-Yi Yu; Zhi-Tang Huang; George W. J. Fleet

Publisher
John Wiley and Sons
Year
2003
Weight
216 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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Ring-Chain Transformation in the 4-Hydroxy-3,4-dihydro-1,2,4triazine Series and a Novel Method for the Synthesis of 1,2,4-Triazine-4-oxides. -Condensation of the hydrazones (I) with aldehydes or ketones (II) affords a tautomeric mixture (III)/(IV) of triazines. The ringchain transformation of these