## Abstmct: The a@ sub&umts at positions 4 and 6 do not erert observable &unmic cffcts on the ting-chain tautomeric mtios of 2,4-or 2,6-aTaqbubstituted-tetmhydm-1,~~. On the other hand, the ekaivnic @ect of the Z-a~yl subs&em is mat&& in all eight seties s&die4 the equilibria CM be desctibed @ the
Ring-chain tautomerism in 1,3-oxazines
✍ Scribed by Fulop, Ferenc; Pihlaja, Kalevi; Mattinen, Jorma; Bernath, Gabor
- Book ID
- 118045222
- Publisher
- American Chemical Society
- Year
- 1987
- Tongue
- English
- Weight
- 611 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0022-3263
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📜 SIMILAR VOLUMES
Gas-phase ring-chain tautomeric equilibria with eight 2-phenyl-substituted perhydro-l,3-oxazines and six 2-arylsubstituted 1,2-dihydro-4H-3,l-benzoxazines were studied by recording their mass spectra under different conditions. Their fragmentation behaviour was also studied using metastable ion anal
The condensation of &-(1) and trans-2-hydroxymethyl-4-cyclohexenvl-l-amine (21 and 2,3-w- (3) cyclo?2.2.l]heptyl&nine (4j and 2,3-d.&&-3\_hydroxymethylbiwith 8 -different-aromatic aldehydes led to ring-chain tautomeric equilibria between epimeric tetrahydro-1,3-oxazines and open-chain Schiff bases.