The crosslinking of a series of thermotropic LC polyesters, consisting of a poly(p-phenylene terephthalate) backbone and flexible aliphatic side chains, by electron beam irradiation was studied as a function of the side-chain composition, side-chain length, and irradiation temperature. For a compari
Rigid rod polymers with stacked electron donor-acceptor side-chains
β Scribed by A. J. M. van Beijnen; R. J. M. Nolte; W. Drenth
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 686 KB
- Volume
- 105
- Category
- Article
- ISSN
- 0165-0513
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Nevertheless, this sequence does not represent a case of thermodynamic equilibrium. The K O and K T (s) phases in PEFBP(n = 9 and 11)s and the S A phase in PEBFP(n = 8 and 10)s are characteristics of the evenodd effect observed in this series of combined LC polyesters. The number of methylene units