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Rigid rod polymers with regularly spaced silicon-centered phthalocyanine units in the backbone

✍ Scribed by Ulrich Lauter; Margit Schulze; Gerhard Wegner

Book ID: 102490772
Publisher: John Wiley and Sons
Year: 1995
Tongue: English
Weight: 332 KB
Volume: 16
Category: Article
ISSN: 1022-1336
DOI: 10.1002/marc.1995.030160402

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✦ Synopsis

We describe the synthesis of new rigid rod polymers possessing a backbone of silicon phthalocyanine units and stiff 4,4'-dioxybiphenyl or 2,6-dioxynaphthalene spacers. These modified phthalocyaninato-polysiloxane derivatives are characterised by mass, absorption and ' k -C P -MAS spectroscopies, differential scanning calorimetry and X-ray powder diffractometry. UV/VIS spectra show only slight differences to the corresponding phthalocyanine monomers, which indicates the absence of excited state interactions between the chromophores within the polymer backbone.

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