𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Rigid polyurethane foams with poly(ethylene terephthalate)/triethanolamine recycling products

✍ Scribed by Michal Kacperski; Tadeusz Spychaj


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
100 KB
Volume
10
Category
Article
ISSN
1042-7147

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✦ Synopsis


A product of the chemical degradation of poly(ethylene terephthalate) (PET) with triethanolamine was used as a polyol component for rigid polyurethane foam synthesis. Miscibility of the product with water, some polar organic solvents and commercial polyols was investigated. Viscosities of the product as a function of temperature as well as in solutions with water and the polyols were examined. The PET chemical recycling product was used instead of the commercial polyol in rigid polyurethane foam formulation. Technological times were defined for the process of the foam synthesis. These foams have density of about 30 kg/m 3 , compression strength in a range of R C = 80±160 kPa and thermal conductivity coefficient ! = 0.028±0.038 W/m K. Rigid polyurethane foams prepared from the product of PET degradation with triethanolamine can be considered as insulation materials.


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Chemical Kinetics, Simulation, and Therm
✍ A. S. Goje; S. Mishra 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 173 KB

## Abstract Reaction of poly(ethylene terephthalate) (PET) waste powder with ethylene glycol (EG) was carried out in a batch reactor at 1 atm pressure and at various temperatures ranging from 100–220 °C at the intervals of 10 °C. Particle size from 50–512.5 μm, reaction time from 30–150 min, amount