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Riboflavine-catalyzed dehydrogenation of dihydrophthalates in the dark

โœ Scribed by Weatherby, Gerald D.; Carr, Daniel O.

Book ID
126204938
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
497 KB
Volume
9
Category
Article
ISSN
0006-2960

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The Riboflavin catalyzed photodecomposit
The Riboflavin catalyzed photodecomposition of 9-aminomethylacridan
โœ George A. Digenis; V.M. Mihranian ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 195 KB

Previously we have reported an unusual oxidative amine fragmentation of 9-aminomethylacridan (g-AMA) (I) to acridine (II) (Eq. 1) by pyridoxal', sodium 1,2-napthoquinone-4sulfonate, and nitrous acid\*. Drawing upon our previous data 132 , we proposed a mechanism for the formation of acridine through