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Rhodium(III) complexes of a substituted 2,2′-bisoxazoline

✍ Scribed by Shee, Nirmal K.; Nag, Samik; Drew, Michael G.B.; Datta, Dipankar

Book ID
123513334
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
566 KB
Volume
405
Category
Article
ISSN
0020-1693

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Schiff's bases derived from 2-aminothiazole and substituted benzaldehydes were reacted with [RhCI(PPh3)3] or [Rh-(/~-CI)(COD)] 2 (COD = 1,5-cyclooctadiene) in the presence of four equivalents of PPh3 to give Rh m cyclometallated complexes of the type [RhHCI{ (X-benzylidene) thiazole}-(PPh3)2], in wh