CβH Activation with Iridium(III) and Rho
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Xiao-Yi Yi; Ka-Wang Chan; Enrique Kwang Huang; Yiu-Keung Sau; Ian D. Williams; W
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Article
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2010
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John Wiley and Sons
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English
β 427 KB
## Abstract Heating [Rh(dtbpy)(ΞΊ~2~β__C,Cβ²__βCH~2~CMe~2~C~6~H~4~)(CH~2~CMe~2~Ph)] (1; dtbpy = 4,4β²βdiβ__tert__βbutylβ2,2β²βbipyridyl) in __p__βxylene at 110 Β°C resulted in the formation of the 2β__tert__βbutylphenyl complex [Rh(dtbpy)(ΞΊ~2~β__C,Cβ²__βCH~2~CMe~2~C~6~H~4~)(C~6~H~4~__t__Buβ2)] (3). Treat