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Rhodium(III) and iridium(III) complexes with 1,2-naphthoquinone-1-oximate as a bidentate ligand: synthesis, structure, and biological activity

✍ Scribed by Stefan Wirth; Christoph J. Rohbogner; Marcin Cieslak; Julia Kazmierczak-Baranska; Stefan Donevski; Barbara Nawrot; Ingo-Peter Lorenz


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
407 KB
Volume
15
Category
Article
ISSN
1432-1327

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## Abstract Heating [Rh(dtbpy)(ΞΊ~2~‐__C,Cβ€²__‐CH~2~CMe~2~C~6~H~4~)(CH~2~CMe~2~Ph)] (1; dtbpy = 4,4′‐di‐__tert__‐butyl‐2,2′‐bipyridyl) in __p__‐xylene at 110 Β°C resulted in the formation of the 2‐__tert__‐butylphenyl complex [Rh(dtbpy)(ΞΊ~2~‐__C,Cβ€²__‐CH~2~CMe~2~C~6~H~4~)(C~6~H~4~__t__Bu‐2)] (3). Treat