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Rhodium(II) acetate-catalyzed Reaction of 2-Amino-4,5-dihydro-3-furancarbonitriles with α-Diazo-β-keto Esters

✍ Scribed by Kenji Yamagata; Keiko Akizuki; Prof. Dr. Motoyoshi Yamazaki

Book ID: 105354966
Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 447 KB
Volume: 340
Category: Article
ISSN: 1615-4150
DOI: 10.1002/prac.19983400706

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## Abstract The reactions of 2‐amino‐4,5‐dihydro‐3‐furancarbonitriles **1a‐d** with α,β‐unsaturated carbonyl compounds in the presence of sodium ethoxide (0.1 equivalent) gave the corresponding Michael adducts **2a‐d**, **3a‐d** and **4a‐d.** Compounds **2a‐d** and **3a‐c** reacted with sodium alko