Rhodium(I) promoted oxygenation of terminal olefins to methyl ketones by molecular oxygen

✍ Scribed by C. Dudley; G. Read

• Book ID: 104237036
• Publisher: Elsevier Science
• Year: 1972
• Tongue: French
• Weight: 216 KB
• Volume: 13
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)85228-x

✦ Synopsis

Aotivetion of moleoular oxygen at mbient temperaturas by metal iona in hmagmmm eyatema has been the mbjeot of muoh rpeoulation, partioulerly in respeot to the interpl~ of wgen end metal ions in blologioal hydrowlations.' Hweverthereareve~few~~ eaples of such reaotions where direot q@nation of the substrate by moleorrlar ory~en has been dmtrated.2

In uiinitial attQlpfto finde goodnwdelforthe bioohemioal process-have md the air sensitive rhodium(I) oaplexer ab(ph3P)f(CO)'