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Rhodium(I) complexes bound to silica via bidentate phosphine ligands

✍ Scribed by Zbirovský, V. ;Kreuzfeld, H. J. ;Čapka, M.

Book ID
112685094
Publisher
Springer
Year
1985
Tongue
English
Weight
193 KB
Volume
29
Category
Article
ISSN
0133-1736

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The synthesis and properties of cationic complexes of general formula [ML2{CH2(Ph2PE)2}]BF4, where M = Pd H and Rh n, L2 = q3-MeC3H4, {P(O)(OR)z}EH (R = Me, Et), COD, (CO)z, (CO)PPh 3 and E = S, Se are described. The methylene proton of the coordinated phosphine sulphide or selenide ligands react wi