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Rhodium(I)-Catalyzed Intramolecular Carbonylative [2+2+1] Cycloadditions and Cycloisomerizations of Bis(sulfonylallene)s

✍ Scribed by Takamasa Kawamura; Fuyuhiko Inagaki; Syu Narita; Yasuhito Takahashi; Shuichi Hirata; Shinji Kitagaki; Chisato Mukai

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
409 KB
Volume
16
Category
Article
ISSN
0947-6539

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Rhodium(I)-Catalyzed Intramolecular Carb
Rhodium(I)-Catalyzed Intramolecular Carbonylative [2+2+1] Cycloaddition of Bis(allene)s: Bicyclo[6.3.0]undecadienones and Bicyclo[5.3.0]decadienones
✍ Fuyuhiko Inagaki; Syu Narita; Takuma Hasegawa; Shinji Kitagaki; Chisato Mukai πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 329 KB πŸ‘ 1 views

## Abstract **No templates needed**: The title reaction makes it easy to construct the bicyclo[6.3.0]undecadienone framework in high yields (see scheme). A template effect is not required to achieve this ring‐closing reaction efficiently. The present method can be applied to the construction of bic