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Rhodium(I) and rhodium(III) phosphine complexes with nonbridging benzenethiolato ligands: preparation, structures, and chemical properties

✍ Scribed by Osakada, Kohtaro; Hataya, Kouji; Yamamoto, Takakazu

Book ID
127189105
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
739 KB
Volume
32
Category
Article
ISSN
0020-1669

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The synthesis and properties of cationic complexes of general formula [ML2{CH2(Ph2PE)2}]BF4, where M = Pd H and Rh n, L2 = q3-MeC3H4, {P(O)(OR)z}EH (R = Me, Et), COD, (CO)z, (CO)PPh 3 and E = S, Se are described. The methylene proton of the coordinated phosphine sulphide or selenide ligands react wi