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Rhodium–copper–TBAF-catalyzed hydroarylation of alkynes with aryl Trimethoxysilanes

✍ Scribed by Baoda Lin; Miaochang Liu; Zhishi Ye; Qin Zhang; Jiang Cheng


Book ID
108285395
Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
472 KB
Volume
50
Category
Article
ISSN
0040-4039

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Palladium-catalyzed cross-coupling react
✍ Zhishi Ye; Miaochang Liu; Baoda Lin; Huayue Wu; Jinchang Ding; Jiang Cheng 📂 Article 📅 2009 🏛 Elsevier Science 🌐 French ⚖ 158 KB

A palladium-catalyzed cross-coupling reaction of aryl trimethoxysilanes with terminal alkynes was described. Thus, di-substituted alkynes were prepared in moderate to good yields. The electron-deficient terminal alkynes also worked well in the procedure.