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Rhodium phosphine complexes as homogeneous catalysts: 14. Asymmetric hydrogenation of a Schiff base of acetophenone — effect of phosphine and catalyst structure on enantioselectivity

✍ Scribed by Sándor Vastag; József Bakos; Szilárd Tórös; Nicholas E. Takach; R. Bruce King; Bálint Heil; László Markó


Publisher
Elsevier Science
Year
1984
Weight
318 KB
Volume
22
Category
Article
ISSN
0304-5102

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Conformational analysis of cationic (R,S
✍ Takashi Hashihayata; T. Punniyamurthy; Ryo Irie; Tsutomu Katsuki; Munetaka Akita 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 920 KB

The structures of (R,S)-and (RR)-(saJen)manganese(III) complexes [(R,S)-2a,b and (R,R)-2a,b] possessing axial chirality as one of their two chiral elements were unambiguously determined by X-ray crystallographic analysis. The basal salen ligands of the complexes were demonstrated to adopt a stepped