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Rhodium generated carbonyl ylides with p-quinones: synthesis of oxa-bridged polycyclic systems

โœ Scribed by Sengodagounder Muthusamy; Srinivasarao Arulananda Babu; Chidambaram Gunanathan; Eringathodi Suresh; Parthasarathi Dastidar; Raksh Vir Jasra


Book ID
108371306
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
335 KB
Volume
57
Category
Article
ISSN
0040-4020

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Novel regioselective synthesis of decahy
โœ Sengodagounder Muthusamy; Chidambaram Gunanathan; Srinivasarao Arulananda Babu ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 74 KB

Intermolecular cycloadditions of five-membered cyclic carbonyl ylides 3 with indole, N-methylindole and N-benzylindole afforded decahydrobenzo[c]carbazole 4a-f or decahydrocyclopenta[c]carbazole 4g-h derivatives with high regioselectivity. With N-benzoylindole and N-sulphonylindole, decahydrobenzo[