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Rhodium Complexes Containing O-Bonded NHxMe2−xCHO (x=0, 1, 2): X-Ray Structure of [Rh(PPh3)3(OCHNHMe)]ClO4

✍ Scribed by Javad S. Sabounchei; Brian T. Heaton; Chacko Jacob; Christopher L. Jones; Anders Olsson; Anthony K. Smith; Lars A. Kloo

Publisher: John Wiley and Sons
Year: 2001
Tongue: German
Weight: 107 KB
Volume: 84
Category: Article
ISSN: 0018-019X
DOI: 10.1002/1522-2675(20011017)84:10<3075::aid-hlca3075>3.0.co;2-d

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✦ Synopsis

This paper commemorates the enormous contribution Luigi M. Venanzi made to inorganic coordination chemistry over many years Displacement of norbornadiene (nbd; bicyclo[2.2.1]hepta-2,5-diene) from [Rh(PPh 3 ) 2 (nbd)]ClO 4 by hydrogenation in the presence of PPh 3 and formamide or Me-substituted derivatives, results in the formation of O-bonded formamide complexes [Rh(PPh 3 ) 3 (OCHNH x Me 2Àx )]ClO 4 (x 0, 1, 2) rather than N-bonded derivatives. These have been characterised by spectroscopic measurements and, in the case of [Rh(PPh 3 ) 3 (OCHNHMe)]ClO 4 , by X-ray crystallography. All undergo oxidative addition with H 2 , and the rates of ligand exchange in the Rh I and Rh III complexes have been determined by magnetisation-transfer measurements.

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