## Abstract Reaction of __ortho__‐xylylbis(__N__‐2,4,6‐trimethylbenzylimidazolinium); xylylbis(__N__‐butylimidazolinium) and __para__‐xylylbis(__N__‐2,4,6‐trimethylbenzylimidazolinium); xylylbis(__N__‐butylimidazolinium) salts with KOBu^__t__^ and [RhCl(COD)]~2~ yields __ortho__‐ and __para__‐xylyl
Rhodium complexes as catalysts for hydrosilylation crosslinking of silicone rubber
✍ Scribed by Marta Heidingsfeldová; Martin Čapka
- Publisher
- John Wiley and Sons
- Year
- 1985
- Tongue
- English
- Weight
- 471 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0021-8995
No coin nor oath required. For personal study only.
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## Abstract Hydrosilylation with well defined piano‐stool iron(II) complexes bearing both N‐heterocyclic carbene and cyclopentadienyl ligands was accomplished with both aldehydes and ketones. Typically, the reduction of aldehydes exhibited good activities (full reduction at 30 °C in 3 h), whereas f
## Abstract A library of organometallic compounds derived from primary and secondary amines cyclometalated by ruthenium(II), rhodium(III) and iridi‐ um(III) was tested in the asymmetric transfer hydrogenation of a number of ketones and imines. All compounds displayed high catalytic activity for the