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Rhodium-Catalyzed Synthesis of Isothiocyanate from Isonitrile and Sulfur.

✍ Scribed by Mieko Arisawa; Masanori Ashikawa; Atsushi Suwa; Masahiko Yamaguchi


Publisher
John Wiley and Sons
Year
2005
Weight
21 KB
Volume
36
Category
Article
ISSN
0931-7597

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Rhodium-Catalyzed Hydroboration Reaction
✍ Siphamandla W. Hadebe; Ross S. Robinson πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 133 KB

## Abstract Rhodium‐catalyzed hydroboration of 1‐octene and __trans__‐4‐octene with sulfur‐ and nitrogen analogues of catecholborane are demonstrated with the use of in situ ^11^B NMR spectroscopy. Our study shows that the sulfur‐ and nitrogen analogues are significantly less prone to disproportion