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Rhodium-catalyzed N-alkylation of amines by a carbon monoxide-water system

โœ Scribed by Yoshihisa Watanabe; Michihiro Yamamoto; Take-aki Mitsudo; Yoshinobu Takegami


Book ID
107858185
Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
122 KB
Volume
19
Category
Article
ISSN
0040-4039

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N-Alkylation of amines with alcohols cat
โœ Ken-ichi Fujita; Zhenzi Li; Naohiro Ozeki; Ryohei Yamaguchi ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 493 KB

A new effective catalytic system consisting of [Cp\*IrCl 2 ] 2 /K 2 CO 3 (Cp\*=pentamethylcyclopentadienyl) for the N-alkylation of primary amines with alcohols has been developed. As an example, the reaction of aniline with benzyl alcohol in the presence of [Cp\*IrCl 2 ] 2 (5.0 mol%Ir) and K 2 CO 3