Rhodium-Catalyzed Multicomponent-Coupling Reactions Involving a Carborhodation—Cross-Coupling Sequence.
✍ Scribed by Ryo Shintani; Takafumi Yamagami; Tamio Hayashi
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 25 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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3-Alkylbicyclo[1.1.1]pent-1-yl Grignard reagents have been using di-or tribromoarenes, coupling products of types 10 and 11 have been obtained. The X-ray structures of four coupled with bromoarenes in the presence of catalytic amounts (0.8-2.0 mol.%) of PdCl 2 (dppf) in diethyl ether model compounds