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Rhodium catalyzed hydrogenation of nitrogen heteroaromatics under water gas shift conditions. Selective synthesis of 1,2,3,4-tetrahydroquinolines and N-formyl-1,2,3,4-tetrahydroisoquinolines

✍ Scribed by Shun-Ichi Murahashi; Yasushi Imada; Yoshiaki Hirai

Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 232 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)95653-3

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✦ Synopsis

Quinolines and isoquinolines are hydrogenated selectively in the nitrogen-containing ring by means of carbon monoxide and water in the presence of catalytic amount of rhodium carbonyl cluster.

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