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Rhodium-catalyzed hydroformylation of styrene at low temperature using potentially hemilabile phosphite–phosphonate ligands

✍ Scribed by Caroline Roch-Neirey; Nathalie Le Bris; Pascale Laurent; Jean-Claude Clément; Hervé des Abbayes

Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 58 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)02028-1

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✦ Synopsis

The synthesis and the effect of phosphite-phosphonate ligands in rhodium-catalyzed hydroformylation of styrene are described. Activity and selectivity of the catalyst are improved, at low temperature, by increasing bulkiness of both phosphite and phosphonate moieties.

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