Rhodium has proven to be an extremely useful metal due to its ability to catalyze an array of synthetic transformations, with quite often-unique selectivity. Hydrogenation, C-H activation, allylic substitution, and numerous other reactions are catalyzed by this metal, which presumably accounts for t
Rhodium-Catalyzed Hydroborations and Related Reactions
โ Scribed by John M. Brown
- Book ID
- 101987867
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 8 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Rhodiumโcatalyzed hydroboration of 1โoctene and __trans__โ4โoctene with sulfurโ and nitrogen analogues of catecholborane are demonstrated with the use of in situ ^11^B NMR spectroscopy. Our study shows that the sulfurโ and nitrogen analogues are significantly less prone to disproportion