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Rhodium-Catalyzed Enantioselective Hydrogenation of Unsaturated Phosphonates by ClickFerrophos Ligands

✍ Scribed by Konno, Takashi; Shimizu, Kenta; Ogata, Kenichi; Fukuzawa, Shin-ichi

Book ID
111647178
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
483 KB
Volume
77
Category
Article
ISSN
0022-3263

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Highly Enantioselective Hydrogenation of
Highly Enantioselective Hydrogenation of β-Acyloxy and β-Acylamino α,β-Unsaturated Phosphonates Catalyzed by Rhodium Phosphane-Phosphite Complexes
✍ M. Ángeles Chávez; Sergio Vargas; Andrés Suárez; Eleuterio Álvarez; Antonio Pizz 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 671 KB

## Abstract The enantioselective hydrogenation of β‐(acyloxy)‐ and β‐(acylamino)vinylphosphonates with rhodium catalysts based on chiral phosphane‐phosphite ligands has been studied. In the case of the β‐(acyloxy)vinylphosphonates, the reaction also produces an achiral phosphonate resulting from th