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Rhodium-Catalyzed Direct C—H Addition of 4,4-Dimethyl-2-oxazoline to Alkenes.

✍ Scribed by Sean H. Wiedemann; Robert G. Bergman; Jonathan A. Ellman

Publisher
John Wiley and Sons
Year
2004
Weight
128 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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✍ Kerstin Schmidt; Jürgen Kopf; Paul Margaretha 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 German ⚖ 213 KB

## Abstract The reactivity of (thiacyclic)‐2,3‐dihydro‐2,2‐dimethyl‐4__H__‐thiopyran‐4‐one (**1a**) in light‐induced cycloadditions to furan (**F**), acrylonitrile (**AN**), or 2,3‐dimethylbut‐2‐ene (**TME**) is compared to that of (carbocyclic) 5,5‐dimethylcyclohex‐2‐enone (**1b**). Whereas for th