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Rhodium-Catalyzed Asymmetric Rearrangement of Alkynyl Alkenyl Carbinols: Synthetic Equivalent to Asymmetric Conjugate Alkynylation of Enones

โœ Scribed by Nishimura, Takahiro; Katoh, Taisuke; Takatsu, Keishi; Shintani, Ryo; Hayashi, Tamio


Book ID
126034114
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
92 KB
Volume
129
Category
Article
ISSN
0002-7863

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Rhodium-Catalyzed Rearrangement of Aryl
โœ Ryo Shintani; Keishi Takatsu; Taisuke Katoh; Takahiro Nishimura; Tamio Hayashi ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 277 KB ๐Ÿ‘ 2 views

A transition-metal-catalyzed isomerization or rearrangement can provide an efficient way to convert readily accessible organic compounds into those with more structural complexity under mild conditions. [1] For example, rhodium-catalyzed isomerization of secondary propargyl alcohols to the correspon