Rhodium-catalyzed asymmetric hydrogenation with aminophosphine ligands derived from 1,1′-binaphthyl-2,2′-diamine
✍ Scribed by Rongwei Guo; Xingshu Li; Jing Wu; Wai Him Kwok; Jian Chen; Michael C.K Choi; Albert S.C Chan
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- French
- Weight
- 69 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0040-4039
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AbstractÐA series of chiral aminophosphine phosphinites DPAMPPs was synthesized from optically active 1,2-diphenyl-2-aminoethanols. The erythro-DPAMPPs were found to serve as excellent ligands for rhodium-catalyzed asymmetric hydrogenation of dehydroamino acid derivatives. For an array of dehydroami
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