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Rhodium-Catalyzed Asymmetric Allylic Substitution with Boronic Acid Nucleophiles.

✍ Scribed by Frederic Menard; Timothy M. Chapman; Chris Dockendorff; Mark Lautens

Publisher
John Wiley and Sons
Year
2007
Weight
39 KB
Volume
38
Category
Article
ISSN
0931-7597

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Rhodium-catalyzed Asymmetric Ring-openin
Rhodium-catalyzed Asymmetric Ring-opening Reactions of N-Boc-azabenzonorbornadiene with N-Substituted Piperazine Nucleophiles
✍ Yuhua Wu; Dingqiao Yang; Heping Zeng; Lei Xie; Lihuan Wu; Haihong Mo; Xiongjun Z πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 133 KB πŸ‘ 1 views

## Abstract Asymmetric ring‐opening reactions of __N__‐Boc‐azabenzonorbornadiene with __N__‐substituted piperazine nucleophiles in the presence of 5 mol% of [Rh(COD)Cl]~2~ and 10 mol% of chiral ligand, (__R__,__S__)‐PPF‐P‐__t__‐Bu~2~, gave the corresponding 1,2‐diamine product in moderate to excell