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Rhodium-Catalyzed Asymmetric 1,4-Addition of Sodium Tetraarylborates to β,β-Disubstituted α,β-Unsaturated Esters

✍ Scribed by Shintani, Ryo; Hayashi, Tamio

Book ID: 127291788
Publisher: American Chemical Society
Year: 2011
Tongue: English
Weight: 208 KB
Volume: 13
Category: Article
ISSN: 1523-7060
DOI: 10.1021/ol102674z

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📜 SIMILAR VOLUMES

ChemInform Abstract: Rhodium-Catalyzed A

ChemInform Abstract: Rhodium-Catalyzed Asymmetric 1,4-Addition of Sodium Tetraarylborates to β,β-Disubstituted α,β-Unsaturated Esters.

✍ Ryo Shintani; Tamio Hayashi 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 57 KB 👁 1 views

## Abstract The asymmetric rhodium‐catalyzed 1,4‐addition of sodium tetraalkylborates to β,β‐disubstituted α,β‐unsaturated esters creates quaternary carbon stereocenters with high enantioselectivity.

Sodium Tetraarylborates as Effective Nuc

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ChemInform Abstract: Sodium Tetraarylbor

ChemInform Abstract: Sodium Tetraarylborates as Effective Nucleophiles in Rhodium/Diene-Catalyzed 1,4-Addition to β,β-Disubstituted α,β-Unsaturated Ketones: Catalytic Asymmetric Construction of Quaternary Carbon Stereocenters.

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ChemInform Abstract: Rhodium-Catalyzed A

ChemInform Abstract: Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboron Reagents to α,β-Unsaturated Esters.

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Chiral Tetrafluorobenzobarrelenes as Eff

Chiral Tetrafluorobenzobarrelenes as Effective Ligands for Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboroxines to β,β-Disubstituted α,β-Unsaturated Ketones

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Chiral Tetrafluorobenzobarrelenes as Eff

Chiral Tetrafluorobenzobarrelenes as Effective Ligands for Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboroxines to β,β-Disubstituted α,β-Unsaturated Ketones

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