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Rhodium-Catalyzed Annulation Reactions of 2-Cyanophenylboronic Acid with Alkynes and Strained Alkenes.

✍ Scribed by Tomoya Miura; Masahiro Murakami

Publisher
John Wiley and Sons
Year
2005
Weight
29 KB
Volume
36
Category
Article
ISSN
0931-7597

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Theoretical elucidation of the rhodium-c
Theoretical elucidation of the rhodium-catalyzed [4 + 2] annulation reactions
✍ Cai-Yun Geng; Ji-Lai Li; Xu-Ri Huang; Hui-Ling Liu; Zhuo Li; Chia-Chung Sun πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 537 KB

## Abstract The reaction mechanism of the Rh‐catalyzed [4 + 2] annulation of 4‐alkynals with isocyanates is unraveled using density functional calculations. The reaction mechanisms of the model system and the real substituted system have been investigated and the results are compared. From our theo