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Rhodium-catalyzed alkylthio exchange reaction of thioester and disulfide

โœ Scribed by Mieko Arisawa; Tomohiro Kubota; Masahiko Yamaguchi

Book ID
108284839
Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
106 KB
Volume
49
Category
Article
ISSN
0040-4039

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Rhodium-catalyzed carbothiolation reacti
Rhodium-catalyzed carbothiolation reaction of 1-alkylthio-1-alkynes
โœ Mieko Arisawa; Yui Igarashi; Yoko Tagami; Masahiko Yamaguchi; Chizuko Kabuto ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 651 KB

A rhodium complex derived from RhH(PPh 3 ) 4 and Me 2 PhP catalyzed the carbothiolation reaction of 1alkylthio-1-alkynes and 1,4-diaryl-1,3-butadiynes giving (Z)-4-alkylthio-4-aryl-3-arylethynyl-3-buten-1-ynes. Terminal alkynes such as 1-decyne and (t-butylthio)acetylene underwent the carbothiolatio