Rhodium catalysed hydroformylation of formaldehyde
- Book ID
- 118396975
- Publisher
- Elsevier Science
- Year
- 1983
- Weight
- 92 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0166-9834
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## Abstract Asymmetric hydroformylation of crotononitrile (**1**) and ally cyanide (**2**) was probed with the view to develop a synthesis for (__R__)β4βaminoβ2βmethylβbutanβ1βol. Hydroformylation of **1** under a variety of conditions mainly led to hydrogenated product. Hydroformylation of **2** w
## Abstract In this theoretical study on rhodiumβcatalysed hydroformylation we examine an unmodified hydridorhodium(I) carbonyl system a together with three variants modified by the model phosphane ligands PF~3~ (system b), PH~3~ (system c) and PMe~3~ (system d), which show increasing basicity on t