Rhodium-catalysed hydroformylation and carbonylation of N-alkenyl-1,3-diaminopropanes

✍ Scribed by David J. Bergmann; Eva M. Campi; W.Roy Jackson; Quentin J. McCubbin; Antonio F. Patti

• Publisher: Elsevier Science
• Year: 1997
• Tongue: French
• Weight: 704 KB
• Volume: 53
• Category: Article
• ISSN: 0040-4020
• DOI: 10.1016/s0040-4020(97)10193-4

✦ Synopsis

The rhodium catalysed reactions of N-alkenyl-|,3-diaminopropanes with H2/CO usually give mixtures of diazabicycloalkanes and aminopropyl lactams. The chemo-and regioselectivity of these reactions are influenced by the choice of ligand and by the ratio of H 2 and CO in the gas mixture and in some cases formation of a single compound can be achieved.