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Rhodium-Catalysed Coupling of Allylic, Homoallylic, and Bishomoallylic Alcohols with Aldehydes and N-Tosylimines: Insights into the Mechanism

✍ Scribed by Nanna Ahlsten; Belén Martín-Matute


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
289 KB
Volume
351
Category
Article
ISSN
1615-4150

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✍ Huimin Liu; QiongMei Zhang; Limin Wang; Xiaofeng Tong 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 283 KB 👁 2 views

## Abstract A new PPh~3~‐catalyzed synthesis of alkyl 2‐[aryl(tosylimino)methyl]acrylates from propiolate and __N__‐tosylimine has been developed. Deuterium‐labelling experiments show that the reaction mechanism involves several hydrogen‐transfer processes, which are not the turnover‐limiting step