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Rhodium catalysed asymmetric hydrosilylation of ketones using phosphorus-containing oxazoline ligands

✍ Scribed by Louise M Newman; Jonathan MJ Williams; Raymond McCague; Gerard A Potter


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
110 KB
Volume
7
Category
Article
ISSN
0957-4166

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πŸ“œ SIMILAR VOLUMES


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A series of new phosphorus-containing oxazoline ligands has been developed. The use of these ligands for asymmetric palladium camlysed allylic substitution of 1,3-diphenylprop-2enyLI-acetate 12 with the sodium salt of dimethylmalonale has been achieved with 90 -94% ee and 88 -99% yield.

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