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Rhodium Carboxylate Catalyzed Decomposition of Vinyldiazoacetates in the Presence of Heterodienes: Enantioselective Synthesis of the 6-Azabicyclo[3.2.2]nonane and 6-Azabicyclo[3.2.2]nonanone Ring Systems.

โœ Scribed by Huw M. L. Davies; L. Mark Hodges


Publisher
John Wiley and Sons
Year
2003
Weight
208 KB
Volume
34
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Use of an Iodonium
โœ R. K. VAID; T. E. HOPKINS ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 29 KB ๐Ÿ‘ 1 views

Use of an Iodonium Ylide in the Synthesis of p-Nitrobenzyl (6R,7S) 3-Hydroxy-8-oxo-7-phenoxyacetamido-1-azabicyclo [4.2.0]octa-2-ene-2-carboxylate. -The title compound (IV), a key intermediate in the synthesis of carbacephalosporins, is prepared by Rh(II)-catalyzed cyclization of the iodonium ylide