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Rhodium and iridium complexes with 2-(diphenylphosphanyl)anilido ligands: reactions with phenylacetylene and dimethyl acetylenedicarboxylate †

✍ Scribed by Dahlenburg, Lutz; Herbst, Konrad

Book ID
120090878
Publisher
The Royal Society of Chemistry
Year
1999
Tongue
English
Weight
284 KB
Volume
22
Category
Article
ISSN
1472-7773

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✍ Anna Penner; Thomas Braun 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 445 KB

## Abstract The treatment of [M(μ‐Cl)(coe)~2~]~2~ (M = Rh, Ir; coe = cyclooctene) with the α‐diketimines ArN=C(Me)C(Me)=NAr (Ar = Ph, Xy; Xy = 2,6‐Me~2~C~6~H~3~) in thf, followed by the addition of CN__t__Bu, gave the α‐diketimine complexes [M(Cl){ArN=C(Me)C(Me)=NAr} (CN__t__Bu)] (1: M = Rh, Ar = P