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Rh(I)-catalyzed asymmetric 1,2-additions of arylboronic acids to isatins with chiral sulfur–alkene hybrid ligands

✍ Scribed by Feng, Xiangqing; Nie, Yanzhao; Zhang, Lanqiong; Yang, Jing; Du, Haifeng

Book ID
125798650
Publisher
Elsevier Science
Year
2014
Tongue
French
Weight
680 KB
Volume
55
Category
Article
ISSN
0040-4039

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Chiral Heterodisulfoxide Ligands in Rhod
Chiral Heterodisulfoxide Ligands in Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to Chromenones
✍ Fuzhong Han; Guihua Chen; Xiangyang Zhang; Jian Liao 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 379 KB 👁 1 views

## Abstract A new family of benzene‐based chiral heterodisulfoxide ligands **L1**–**L5** was synthesized in a single step. These disulfoxide ligands were applied in the rhodium‐catalyzed asymmetric 1,4‐addition of arylboronic acids to chromenones. The addition of diverse arylboronic acids to chrome