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Rheology of polymeric solutions I. Zero shear conditions

✍ Scribed by V. M. Yasnovsky

Publisher: John Wiley and Sons
Year: 2002
Tongue: English
Weight: 176 KB
Volume: 85
Category: Article
ISSN: 0021-8995
DOI: 10.1002/app.10736

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## Abstract Application of shear is found to increase the rate of solution polymerization of acrylonitrile in N,N‐dimethyl formamide (DMF) initiated by benzoyl peroxide by as much as 400 percent of the value in absence of shear. The solvent DMF acts as an inert and maintains a homogeneous reaction