Rheological behaviour of binary mixtures of polystyrene-block-polyisoprene copolymers in the disordered state
โ Scribed by Deog Man Baek; Chang Dae Han
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 992 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0032-3861
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๐ SIMILAR VOLUMES
Abstraet--A calorimetric study was made of micelle formation by a polystyrene-b-polyisoprene block copolymer in n-hexadecane which is a selectively bad solvent for polystyrene. A value of -44.0 + 4.0 kJ mol-~ was obtained for the enthalpy of micellisation, in good agreement with a value of -40.7 +2.
Dynamic light scattering (DLS) has been used to explore the properties of asymmetric styrene-isoprene (SI) block copolymers in concentrated solutions. Concentrations were always well below those necessary to access the order-disorder transition in neutral good solvents. The samples include SI(10-50)