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Rheological behavior of SAN/PC blends under extremely high shear rate

โœ Scribed by Hideroh Takahashi; Takaaki Matsuoka; Takashi Ohta; Kenzo Fukumori; Toshio Kurauchi; Osami Kamigaito


Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
765 KB
Volume
37
Category
Article
ISSN
0021-8995

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โœฆ Synopsis


Extremely high shear rate processing was applied to the compound system of acrylonitrilestyrene copolymer/polycarbonate (SAN/PC). The viscosity was measured against the shear rate The first non-Newtonian region, the second Newtonian region and second non-Newtonian region were observed in the compound system. The occurrence of these regions are very similar to those in the parent polymers, SAN and PC. For the calculation of the viscosity-shear rate curve, a concentric multilayer model was proposed. It gives good agreement between the calculated value and the measured one. A new mechanism for the occurrence of the non-Newtonian, second Newtonian, and second non-Newtonian regions was proposed. Nuclear spin-spin relaxation time measured on SAN, T2, seems to be consistent with the consideration that the occurrence of non-Newtonian region, second Newtonian region, and second non-Newtonian region are caused, respectively, by the disentanglement, near saturation of disentanglement associated with snapping of macromolecules, and reentanglement through recoiling of snapped macromolecules, and further snapping of the macromolecules, which is inconsistent with the proposed explanation.


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