## Abstract A Fourier‐transform Raman‐sepectroscopy‐based rheo‐optical system was used to study the process of uniaxial stretching of poly(vinylidene fluoride) (PVF~2~). This rheo‐optical system made possible to reduce the rate of stretching and favoured the acquisition of a higher number of spectr
✦ LIBER ✦
Rheo-optical Raman study of chain deformation in uniaxially stretched bulk polyethylene
✍ Scribed by J.C. Rodríguez-Cabello; J.C. Merino; T. Jawhari; J.M. Pastor
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 724 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0032-3861
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The Raman spectrum of polyethylene is known to be mainly sensitive to the conformational state of the polymer chain. At room temperature, most of the vibrations of the polyethylene Raman spectrum are intrinsically reflecting only one-dimensional order along the chain length. Based on the latter, we