Rhenium(V)−Salen Complexes: Configurational Control and Ligand Exchange
✍ Scribed by van Bommel, Kjeld J. C.; Verboom, Willem; Kooijman, Huub; Spek, Anthony L.; Reinhoudt, David N.
- Book ID
- 126928481
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 145 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0020-1669
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The kinetics of pyridine exchange on truns-[MO,(py),]' have been followed by 'H-NMR in CD,NO, for M = Re, Tc: k298/s-' = (5.5 i 0.1) x 0.04 i 0.02; A H #/kJmol-' = 11 1 f-3, 101 f 9; dSf/JK-'mol-' = +28 \* 10, +68 \* 35. For the ReV complex, pyridine and oxygen exchanges have been measured simultane
A series of monooxo-rhenium(V) mixed-ligand complexes containing bidentate functionalized phosphines and tridentate Schiff base (SB) ligands have been synthesized via ligand-exchange reactions starting from labile Re(V) precursors. A convenient route of synthesis is provided by the isolation of inte